FU Pei, CAO Ziqiang, CHEN Ying, XIE Yang, LIU Qingshan, CHEN Yisong
Journal of Engineering Thermophysics. 2025, 46(8): 2520-2531.
Solid oxide fuel cell (SOFC) is an innovative green energy technology. It efficiently uses hydrogen energy and has a wide range of applications, which helps transform China’s energy structure. For planar anode-supported SOFCs, the gradient anode design is considered to be an important structural feature that can enhance the overall performance. This study numerically investigates the gradient composition anode SOFC. Under isothermal conditions, three-dimensional multi-physics coupling models are established. These models simulate the gas transport and electrochemical reaction processes in the SOFC. By comparing the mass transfer and electrical performance of homogeneous composition anode and gradient composition anode SOFCs, this study analyzes the influence mechanism of gradient composition anodes on SOFC performance. This analysis reveals the superiority of the gradient composition anode design. It is found that in the homogeneous composition anode SOFCs, as the volume fraction of electronic conductor increases, the hydrogen mole fraction in the anode channels and porous anodes increases. The hydrogen mole fraction distribution in the gradient composition anode is higher than that in the homogeneous composition anode. This indicates that the gradient composition anode can effectively improve the cell’s mass transfer performance. Compared with homogeneous composition anode SOFCs, the gradient composition anode SOFC doesn’t show significant advantages in reducing activation polarization and ohmic polarization losses. However, it can significantly reduce the concentration polarization losses, thus lowering the total polarization loss of the SOFC anode. In this study, the maximum output power density of the gradient composition anode SOFC can reach 1.24 W·cm−2, which is 28.40%, 9.13%, and 10.68% higher than that of the homogeneous composition anode SOFCs with electronic conductor volume fractions of 0.65, 0.50, and 0.40 respectively. Evidently, the gradient composition anode design can significantly improve the electrical performance of SOFC. This research can provide theoretical guidance for the optimization design of gradient anode compositions in SOFCs.