WANG Zhenqiang, LI Yanxia, LIU Zhongliang, LI Yi, YU Fengjiao
2025, 46(4): 1041-1047.
The initial frosting phenomenon is a spatially discontinuous phase transformation and nucleation process. The cold surface temperature and characteristics have a direct and significant impact on the frosting phenomenon. It has been shown that the effect of a superhydrophobic surface on frost formation on a cryogenic cold surface is much less obvious than that on a general cold surface. To understand the influences of surface characteristics on frost formation at −190∼ −30°C, the growth and morphological characteristics of frost crystals on hydrophilic and superhydrophobic surfaces at the initial stage of frost formation are experimentally studied. Four frost formation patterns are observed: cold surface condensation frosting, air boundary layer condensation frosting, cold surface sublimation frosting, and air boundary layer sublimation frosting. The four frost formation modes appear independently or co-exist on cold surfaces of different temperatures, and have important effects on the morphology of frost crystals. The cold surface properties (contact angles) have a significant effect on frost formation patterns within a specific range. The cold surface condensation frosting mode is only observed on hydrophilic surfaces at −30°C. The liquid air is only observed on superhydrophobic surfaces at −190°C. The initial frost crystal morphology changes with the cold surface temperature, frost formation mode, and surface properties, and it can be roughly divided into four forms: hexagonal, pine needle, cluster, and flocculant.